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What should you do if you believe that a relative was poisoned by her husband? She had complained about being abused by her husband. She fell suddenly ill and had odd toxicology results, never fully explained. After she passed away, her husband rushed to have her cremated.
You can report your suspicions to the police. If you have the money and want to spend it, you can consider hiring (or helping a family member hire) a forensic pathologist to review the medical records and cause of death. There's really not much more you can do.